User just prints PDF documents (only Qweb PDF reports supported) as usual, but signed PDF is automatically downloaded if this document model is configured as indicated above. If 'Save as attachment' is configured, signed PDF is saved as attachment and next time saved one is downloaded without signing again. This is appropiate when signing date is important, for example, when signing customer invoices. You can try the signing with the demo report that is included for customers called "Test PDF certificate".